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خانه مقالات-Article مقالات شیمی-Chemistry Articles Experimental Study and Modeling of Methane Hydrate Formation Induction Time in the Presence of Ionic Liquids
Experimental Study and Modeling of Methane Hydrate[taliem.ir]

Experimental Study and Modeling of Methane Hydrate Formation Induction Time in the Presence of Ionic Liquids

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Gas hydrate formation has been referred as unfavorable phenomenon since it leads to blockage of pipelines. To prevent formation of these compounds, several methods are normally pursued including system heating, depressurization, water removal, and use of gas hydrate  formation inhibitors. The latter technique may be the most practical method for this purpose. Two types of inhibitors are generally used in the industry: thermodynamic inhibitors and kinetic ones. Thermodynamic inhibitors (such as ethylene glycol and methanol) shift the hydrate-liquid-vapor- (HLV) equilibrium curve to lower temperature and higher-pressure conditions. Kinetic inhibitors (such as PVP, PVCap) delay the hydrate nucleation and growth rates. There are some evidences that ionic liquids have dual inhibition effects. In this communication, we use three ionic liquids including (BMIM-BF4), (BMIM-DCA), and (TEACL). Methane hydrate formation induction time in the presence of different concentrations of these three ionic liquids is kinetically investigated in this work. Consequently, the effects of initial pressure and ionic liquids concentration on the induction time can be evaluated. In addition, a three parameter semi-empirical model is developed on the basis of chemical kinetics theory. Finally, it is shown that the proposed semi-empirical model has a good accuracy in comparison with the experimental data

توضیحات محصول

ABSTRACT
Gas hydrate formation has been referred as unfavorable phenomenon since it leads to blockage of pipelines. To prevent formation of these compounds, several methods are normally pursued including system heating, depressurization, water removal, and use of gas hydrate  formation inhibitors. The latter technique may be the most practical method for this purpose. Two types of inhibitors are generally used in the industry: thermodynamic inhibitors and kinetic ones. Thermodynamic inhibitors (such as ethylene glycol and methanol) shift the hydrate-liquid-vapor- (HLV) equilibrium curve to lower temperature and higher-pressure conditions. Kinetic inhibitors (such as PVP, PVCap) delay the hydrate nucleation and growth rates. There are some evidences that ionic liquids have dual inhibition effects. In this communication, we use three ionic liquids including (BMIM-BF4), (BMIM-DCA), and (TEACL). Methane hydrate formation induction time in the presence of different concentrations of these three ionic liquids is kinetically investigated in this work. Consequently, the effects of initial pressure and ionic liquids concentration on the induction time can be evaluated. In addition, a three parameter semi-empirical model is developed on the basis of chemical kinetics theory. Finally, it is shown that the proposed semi-empirical model has a good accuracy in comparison with the experimental data.

INTRODUCTION

Gas hydrates are belonging to the clathrates families, which are composed of water molecules and some guest molecules like methane,  ethane, propane, etc. Under appropriate conditions which are high pressures and low temperatures conditions, some guest molecules which  are gases with appropriate sizes and shapes are trapped in the cavities which are formed by water molecules that are connecting together by  hydrogen bonding and gas hydrates are formed. From the discovery of hydrates in 1810 until present, gas hydrates are one of the   interesting fields for scientists to study. Gas hydrates have many advantages and some disadvantages. The major problem in hydrate  formation is leading to gas pipelines. In 1934, Hammerschmidt expressed that in high pressures and low temperatures in pipelines gas  hydrates are formed that cause pipeline blockage, safety problems, pressure losses and huge economic losses. Since 1934, hydrates were  known as harmful phenomena and for avoiding hydrate formations in pipelines several methods such as: system heating, depressurization,  water removal and use of inhibitors were developed.

Year: 2013

Publisher :  2nd National Iranian Conference on Gas Hydrate (NICGH)

By : Ali Rasoolzadeh , Jafar Javanmardi

File Information: English Language/ 10 Page / size: 560 KB

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سال : 1392

ناشر : دومین کنفرانس ملی هیدرات گاز (NICGH)

کاری از : علی رسول زاده، جعفر جوانمردی

اطلاعات فایل : زبان انگلیسی / 10 صفحه / حجم : KB 560

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